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| Names | |
|---|---|
| IUPAC name 1,1,1,3,3,3-hexachloropropanone | |
| Other names perchloroacetone HCA | |
| Identifiers | |
3D model (JSmol) | |
| ChEBI | |
| ChEMBL | |
| ChemSpider | |
| ECHA InfoCard | 100.003.754  |
| EC Number |
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| KEGG | |
PubChem CID | |
| RTECS number |
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| UNII | |
| UN number | 2661 |
CompTox Dashboard (EPA) | |
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SMILES
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| Properties | |
| C3Cl6O | |
| Molar mass | 264.75 g/mol |
| Density | 1.7434 g/cm3[1] |
| Melting point | −2 °C (28 °F; 271 K) |
| Boiling point | 204 °C (399 °F; 477 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Hexachloroacetone is an organic compound with the formula (Cl3C)2CO. It is also called hexachloropropanone or perchloroacetone. Numbers indicating the position of the chlorine-atoms are generally omitted as all the possible positions are substituted with chlorine. It is a colorless liquid, slightly soluble in water.
The main use of hexachloroacetone is as a pesticide. For the use of hexachloroacetone in the preparation of a novel insect repellent see Perkow reaction. The industrial route to hexafluoroacetone involves treatment of hexachloroacetone with HF:[2]
- (CCl3)2CO + 6 HF → (CF3)2CO + 6 HCl
See also
- Chloroacetone
- Dichloroacetone
References
- ^ CRC Handbook of Chemistry and Physics, Internet Version, CRC Press (2005)
- ^ Günter Siegemund, Werner Schwertfeger, Andrew Feiring, Bruce Smart, Fred Behr, Herward Vogel, Blaine McKusick (2002). "Fluorine Compounds, Organic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a11_349. ISBN 3527306730.