Glucal[1]  |
| Names |
| IUPAC name (2R,3S,4R)-2-(Hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol |
| Identifiers |
| | |
3D model (JSmol) | |
| ChemSpider | |
| ECHA InfoCard | 100.032.949  |
| | |
| | |
InChI=1S/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6+/m1/s1  Key: YVECGMZCTULTIS-PBXRRBTRSA-N InChI=1/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6+/m1/s1 Key: YVECGMZCTULTIS-PBXRRBTRBT
|
SMILES C1=CO[C@@H]([C@H]([C@@H]1O)O)CO
|
| Properties |
| | C6H10O4 |
| Molar mass | 146.1412 |
| Melting point | 58 to 60 °C (136 to 140 °F; 331 to 333 K) |
| Hazards |
| S-phrases (outdated) | S22 S24/25 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
| | |
Glucal is the glycal formed from glucose.[2] It is a chemical intermediate in the synthesis of a variety of oligosaccharides.[3]
Glucal and its derivatives can be converted to other chemically useful sugars using the Ferrier rearrangement.
References
- ^ Glucal at Sigma-Aldrich
- ^ E.Fischer and K. Zasch. Sitzber. kgl.preuss. Akad Wiss., 16,311 (1913)
- ^ Seeberger, P.H., et al. Aldrichimica Acta 30, 75, (1997)
This article is copied from an
article on Wikipedia® - the free encyclopedia created and edited by its online user community. The text was not checked or edited by anyone on our staff. Although the vast majority of Wikipedia® encyclopedia articles provide accurate and timely information, please do not assume the accuracy of any particular article. This article is distributed under the terms of
GNU Free Documentation License.
All content on this website, including dictionary, thesaurus, literature, geography, and other reference data is for informational purposes only. This information should not be considered complete, up to date, and is not intended to be used in place of a visit, consultation, or advice of a legal, medical, or any other professional.
)
