) Crystals of scandium(III) chloride hexahydrate | |
| Names | |
|---|---|
| IUPAC name Scandium(III) chloride | |
| Other names scandium chloride scandium trichloride | |
| Identifiers | |
3D model (JSmol) | |
| ChemSpider | |
| ECHA InfoCard | 100.030.714  |
PubChem CID | |
| RTECS number |
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| UNII | |
CompTox Dashboard (EPA) | |
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SMILES
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| Properties | |
Chemical formula | ScCl3 |
| Molar mass | 151.31 g/mol |
| Appearance | grayish-white crystals |
| Density | 2.39 g/mL, solid |
| Melting point | 960 °C (1,760 °F; 1,230 K)[1] 63 °C (hexahydrate) |
| soluble | |
| Solubility in other solvents | insoluble in EtOH |
| Hazards | |
| Main hazards | irritant |
| Safety data sheet | External MSDS |
| NFPA 704 (fire diamond) | |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 3980 mg/kg (mouse, oral) |
| Related compounds | |
Related compounds | Scandium(III) fluoride Scandium(III) nitrate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Scandium(III) chloride is the inorganic compound with the formula ScCl3. It is a white, high-melting ionic compound, which is deliquescent and highly water-soluble.[2] This salt is mainly of interest in the research laboratory. Both the anhydrous form and hexahydrate (ScCl3•6H2O) are commercially available.
Structure
ScCl3 crystallises in the layered BiI3 motif, which features octahedral scandium centres.[3] Monomeric ScCl3 is the predominant species in the vapour phase at 900 K, the dimer Sc2Cl6 accounts for approximately 8%.[4] The electron diffraction spectrum indicates that the monomer is planar and the dimer has two bridging Cl atoms each Sc being 4 coordinate.[4]
Reactions
ScCl3 dissolves in water to give [Sc(H2O)6]3+ ions. In fact, samples of ScCl3 converts to this hexahydrate upon exposure to air. The structure of the hexahydrate is trans-[ScCl2(H2O)4]Cl·2H2O.[5] With the less basic ligand tetrahydrofuran, ScCl3 yields the adduct ScCl3(THF)3 as white crystals. This THF-soluble complex is used in the synthesis of organoscandium compounds.[6] ScCl3 has been converted to its dodecyl sulfate salt, which has been investigated as a "Lewis acid-surfactant combined catalyst" (LASC) in aldol-like reactions.[7]
Reduction
Scandium(III) chloride was used by Fischer et al. who first prepared metallic scandium by electrolysis of a eutectic melt of scandium(III) chloride and other salts at 700-800 °C.[8]
ScCl3 reacts with scandium metal to give a number of chlorides where scandium has an oxidation state <+3, ScCl, Sc7Cl10, Sc2Cl3, Sc5Cl8 and Sc7Cl12.[2][9] For example, reduction of ScCl3 with scandium metal in the presence of caesium chloride gives the compound CsScCl3 which contain linear chains of composition ScIICl3−, containing ScIICl6 octahedra sharing faces.[10]
Uses
Scandium(III) chloride is found in some halide lamps, optical fibers, electronic ceramics, and lasers.[11]
References
- ^ Frederikse, H.P.R.; Lide, David R. (1998). CRC Handbook of Chemistry and Physics (78th Edition)
- ^ a b Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
- ^ Crystal Structure of ScCl3 Refined from Powder Neutron Diffraction Data, Fjellvåg, H., Karen, P., Acta Chemica Scandinavica, 48, 294-297, doi:10.3891/acta.chem.scand.48-0294
- ^ a b Haaland A., Martinsen K-G, Shorokhov D.J, Girichev G.V., Sokolov V.I, J. Chem. Soc., Dalton Trans., 1998, 2787 - 2792, doi:10.1039/a803339k
- ^ The Rare Earth Elements, Fundamentals and Applications David A. Atwood, 2012, John Wiley & Sons Inc, ISBN 9781119950974
- ^ Manzer, L. E., "Tetrahydrofuran Complexes of Selected Early Transition Metals", Inorganic Syntheses, 1982, volume 21, page 135-40.doi:10.1002/9780470132524.ch31
- ^ Manabe, Kei; Mori, Yuichiro; Kobayashi, Shū (1999). "Effects of Lewis acid-surfactant-combined catalysts on aldol and Diels-Alder reactions in water". Tetrahedron. 55 (37): 11203–11208. doi:10.1016/S0040-4020(99)00642-0.
- ^ Fischer, Werner; Brünger, Karl; Grieneisen, Hans (1937). "Über das metallische Scandium". Zeitschrift für anorganische und allgemeine Chemie. 231 (1–2): 54–62. doi:10.1002/zaac.19372310107.
- ^ Corbett, J.D. (1981). "Extended metal-metal bonding in halides of the early transition metals". Acc. Chem. Res. 14 (8): 239–246. doi:10.1021/ar00068a003.
- ^ Meyer, Gerd.; Corbett, John D. (1981). "Reduced ternary halides of scandium: RbScX3 (X = chlorine, bromine) and CsScX3 (X = chlorine, bromine, iodine)". Inorganic Chemistry. 20 (8): 2627–2631. doi:10.1021/ic50222a047. ISSN 0020-1669.
- ^ Metal Suppliers Online. (2000). Scandium Chloride